Describe melting and boiling in terms of energy input without a change in temperature

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IGCSE Physics - Melting and Boiling

2.2.3 Melting, Boiling and Evaporation

This section describes the processes of melting and boiling, focusing on how energy input affects these changes without a change in temperature.

Melting

Definition

Melting is the process by which a solid changes into a liquid. This occurs when the solid is heated.

Energy Input and Melting Point

When a solid is heated, the particles within it gain kinetic energy and vibrate more vigorously. The melting point is the specific temperature at which the particles in the solid gain enough kinetic energy to overcome the intermolecular forces holding them in a fixed lattice structure. At this point, the solid transitions into a liquid.

Energy Required for Melting

The energy required to melt a substance is called the latent heat of fusion. This energy is absorbed by the solid and does not cause a change in temperature. Instead, it is used to break the bonds between the particles.

Diagram

Suggested diagram: A block of ice being heated, with labels indicating the temperature remaining constant during melting and the energy input being used for the phase change.

Equation

The amount of energy (Q) required to melt a substance is given by the equation:

Quantity Formula
Mass of substance (m) kg
Latent heat of fusion (Lf) $J/kg$
Energy input (Q) $Q = mL_f$

Boiling

Definition

Boiling is the process by which a liquid changes into a gas (or vapour). This occurs when the liquid is heated.

Boiling Point

The boiling point is the specific temperature at which the vapor pressure of the liquid equals the surrounding atmospheric pressure. At this point, the liquid molecules have enough kinetic energy to escape from the liquid phase and enter the gaseous phase.

Energy Input and Boiling Point

Similar to melting, the temperature of the liquid remains constant during boiling, even though energy is being added. This energy is used to overcome the intermolecular forces holding the liquid molecules together, allowing them to transition into the gaseous state. The energy required for this phase change is the latent heat of vaporization.

Energy Required for Boiling

The energy required to boil a substance is called the latent heat of vaporization. This energy is absorbed by the liquid and does not cause a change in temperature. It is used to overcome the intermolecular forces and allow the molecules to escape into the gaseous phase.

Diagram

Suggested diagram: A liquid being heated, with labels indicating the temperature remaining constant during boiling and the energy input being used for the phase change.

Equation

The amount of energy (Q) required to boil a substance is given by the equation:

Quantity Formula
Mass of substance (m) kg
Latent heat of vaporization (Lv) $J/kg$
Energy input (Q) $Q = mL_v$

Evaporation

Definition

Evaporation is a type of boiling that occurs at a temperature below the boiling point of a liquid. It happens when some of the liquid molecules gain enough kinetic energy to escape into the gaseous phase.

Energy Input and Evaporation

Even at temperatures below the boiling point, liquid molecules are constantly gaining kinetic energy. Some of these molecules will have enough energy to overcome the intermolecular forces and escape into the air as a gas. The energy required for evaporation is the latent heat of vaporization.

Factors Affecting Evaporation

Several factors can affect the rate of evaporation, including:

  • Temperature: Higher temperatures lead to a faster rate of evaporation.
  • Surface area: A larger surface area allows for more molecules to escape, increasing the rate of evaporation.
  • Humidity: Higher humidity means the air is already saturated with water vapour, slowing down the rate of evaporation.
  • Airflow: Moving air removes water vapour from the surface, promoting faster evaporation.