Organic chemistry - Formulae, functional groups and terminology (3)
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1.
State that a structural formula is an unambiguous description of the way the atoms in a molecule are arranged, including CH2=CH2, CH3CH2OH, and CH3COOCH3. Explain what is meant by the term 'unambiguous' in this context.
A structural formula is an unambiguous description of the way the atoms in a molecule are arranged because it shows the connectivity of the atoms and the type of bonds between them. 'Unambiguous' means that the structural formula provides a single, definite representation of the molecule's structure. There is only one way to draw a structural formula for a given molecule. This eliminates any possibility of different interpretations or isomers being represented by the same formula. For example, CH2=CH2 (ethene), CH3CH2OH (ethanol), and CH3COOCH3 (methyl acetate) each have only one possible structural formula, ensuring a clear and precise representation of their molecular arrangement.
2.
A student is given a displayed formula for a molecule: H
N
H. Draw the displayed formula and state the name of the compound. What does the displayed formula tell us about the compound's chemical formula?
Displayed Formula:
N
H
Name of Compound: Ammonia
What the displayed formula tells us: The displayed formula shows the actual number of atoms of each element in one molecule. The chemical formula for ammonia is NH3, indicating one nitrogen atom and three hydrogen atoms. The displayed formula confirms this, showing one nitrogen atom bonded to three hydrogen atoms.
3.
A student states: "All alkanes have the same boiling point." Explain why this statement is incorrect, referring to the characteristics of homologous series. Also, describe how the boiling point changes as you move down the alkane series.
The statement "All alkanes have the same boiling point" is incorrect because homologous series do not have the same physical properties. While they share a common functional group (the C-H bond) and a common general formula (CnH2n+2), the size of the molecules within the series increases as 'n' increases. Larger molecules have greater intermolecular forces (specifically, van der Waals forces) due to a larger surface area for contact. This leads to stronger intermolecular forces and therefore higher boiling points.
As you move down the alkane series (i.e., as 'n' increases), the boiling point increases. This is because the larger molecules have stronger London dispersion forces. The boiling point trend is predictable and consistent with the characteristics of a homologous series – a gradual change in physical properties with each incremental addition of a -CH2- unit.