Stoichiometry - The mole and the Avogadro constant (3)
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1.
Explain, in terms of the structure of matter, why the mole is a useful unit for chemists.
The mole is a useful unit for chemists because it relates the macroscopic properties of a substance (e.g., mass, volume) to the microscopic world of atoms, ions, and molecules.
Structure of Matter and the Mole:
- Atoms, ions, and molecules are incredibly small. It's impractical to count them individually.
- The mole provides a convenient way to count these particles. One mole contains a fixed number of particles (Avogadro's number).
- This allows chemists to relate the mass of a substance to the number of particles present. For example, knowing the molar mass of a compound (grams per mole) allows us to calculate the number of moles in a given mass of the compound, and vice versa.
- Many chemical reactions occur on a molecular or ionic level. Using moles allows us to accurately predict the amounts of reactants and products involved in a reaction based on the number of particles.
In essence, the mole bridges the gap between the macroscopic and microscopic worlds, making it a fundamental and essential unit in chemistry.
2.
A student measures a mass of magnesium carbonate (MgCO3) as 2.49 g. Calculate the number of moles of magnesium carbonate in the sample.
Given:
- Mass of MgCO3 = 2.49 g
- Molar mass of MgCO3 = 12.01 (Mg) + 12.01 (C) + 3 * 16.00 (O) = 39.01 g/mol
Calculation:
Number of moles (n) =
n = 2.49 g / 39.01 g/mol = 0.0645 mol
Answer: The number of moles of magnesium carbonate is 0.0645 mol.
3.
Question 1
The empirical formula of a hydrocarbon is C2H6. The molar mass of the compound is 58 g/mol. Determine the molecular formula.
Solution:
- Calculate the molar mass of the empirical formula (C2H6):
M(C2H6) = (2 x 12) + (6 x 1) = 24 + 6 = 30 g/mol
- Calculate the ratio of the molar mass of the compound to the molar mass of the empirical formula:
Ratio = 58 g/mol / 30 g/mol = 1.93 (approximately)
- Multiply the subscripts in the empirical formula by the ratio to obtain the molecular formula:
Molecular Formula = C2H6 x 1.93 ≈ C3.86H7.68. Since we need whole numbers, we round to the nearest whole number.
- Therefore, the molecular formula is C4H8.
Answer: C4H8